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Beilstein J. Org. Chem. 2019, 15, 371–377, doi:10.3762/bjoc.15.33
Graphical Abstract
Figure 1: Exemplar C3-symmetric peptide scaffolds reported in the literature.
Scheme 1: Preparation of compound 7 from L-serine (3).
Scheme 2: Preparation of the trimerized product 9.
Scheme 3: Synthesis of compound 11 via Negishi cross-coupling reaction.
Scheme 4: Synthesis of C3-symmetric trimers 12, 13 and 14.
Beilstein J. Org. Chem. 2018, 14, 2537–2544, doi:10.3762/bjoc.14.230
Figure 1: Various alkaloids containing propellane frame work.
Scheme 1: Synthesis of the star-shaped norbornene derivative 11 via trimerization.
Figure 2: Selected list of ruthenium-based catalysts used for ROM.
Scheme 2: Synthesis of the C3-symmetric molecule 15 bearing propellane moieties via trimerization and RCM.
Scheme 3: Synthesis of C3-symmetric molecule 21 bearing propellane moieties via trimerization and RCM.